Chinese researchers have developed a new aluminosilicate zeolite, ZMQ-1, which features a unique intersecting meso-microporous channel system that is expected to enhance catalytic processes in the petrochemical industry.
The study, published in Nature on Wednesday, highlights ZMQ-1 as the first aluminosilicate zeolite with interconnected intrinsic 28-ring mesopores. This breakthrough overcomes long-standing challenges related to zeolite pore size limitation, stability, and catalytic efficiency.
Zeolites are crystalline materials renowned for their applications in ion exchange, adsorption, and catalysis. However, their microporous structure limits their use in processing larger molecules. Researchers have addressed this limitation by developing a zeolite with intrinsic mesopores while maintaining stability and acidity.
ZMQ-1 zeolite was developed by a research team at the Qingdao Institute of Bioenergy and Process Technology of the Chinese Academy of Sciences. It has larger holes, allowing large molecules to pass through unimpeded. At the same time, it has strong stability and can stably perform molecular screening even in special environments such as high temperature and high moisture.
According to the researchers, ZMQ-1 makes the chemical production process more efficient and is environmentally friendly. For example, in the process of oil processing, the material can more efficiently convert heavy oil into gasoline and diesel, with a conversion rate of more than 80 percent, far higher than the current average level of 65 percent.
At the same time, the conversion method using this material can also reduce the production of by-products such as coke and waste gas, making the process greener.
Furthermore, in the field of biomass treatment, this type of new material can convert biological waste into chemicals with application value such as diesel and alcohol. In the fields of fine chemicals and gas storage, it can also save energy and reduce consumption for industrial production, thereby providing new opportunities for promoting the upgrading of industries such as petrochemicals and biomass utilization, and providing important support for the development of green chemistry.
Breakthrough zeolite structure to unleash superior heavy oil cracking efficiency
